Doped semiconducting polymer nanoantennas for tunable organic plasmonics

نویسندگان

چکیده

Abstract Optical nanoantennas are often based on plasmonic resonances in metal nanostructures, but their dynamic tunability is limited due to the fixed permittivity of conventional metals. Recently, we introduced PEDOT-based conducting polymers as an alternative materials platform for plasmonics and metasurfaces. Here, expand organic systems a wider class doped polythiophene-based semiconducting polymers. We present nanodisks PBTTT polymer with dicationic salt, enabling high doping level around 0.8 charges per monomer, demonstrate that they can be used nanooptical antennas via redox-tunable resonances. The arise from being optically metallic its state dielectric non-conducting undoped state. controllable over 1000 nm wavelength range by changing dimensions nanodisks. Furthermore, optical response reversibly tuned modulating polymer. Simulations corroborate experimental results reveal possibility also modulate nearfield nanoantennas.

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ژورنال

عنوان ژورنال: Communications materials

سال: 2022

ISSN: ['2662-4443']

DOI: https://doi.org/10.1038/s43246-022-00268-w